The POS assumes the buyer is 'on site' for purchase, so it will add your local tax. If you are going to ship the order, press the blue Ship button and it will add Shipping charge and the destination tax.
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Multiple Addresses
Add Multiple Addresses on Ship To Order At Checkout.
You can add a new address for a ship to order on the POS check out. This address will also be available for a member when they login to create an order.
Add Multiple Addresses on the Member Profile
Alternatively, you can click on the customer profile and add multiple addresses that way. Click on Customers > Enter the Name and click into profile.
Then Click Edit.
In the customer profile, scroll down to Shipping Addresses section. Add new address and review billing address. Then click Update and Return.